Polyisoprenepolyols from Fruiting Bodies of <italic style="font-style: italic">Gymnopilus spectabilis</italic>

Shuang WANG; Yan-qiu SONG

doi:10.13422/j.cnki.syfjx.20192015

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Polyisoprenepolyols from Fruiting Bodies of Gymnopilus spectabilis

Resource and Quality Evaluation | 更新时间：2021-02-09

- Polyisoprenepolyols from Fruiting Bodies of Gymnopilus spectabilis
- Chinese Journal of Experimental Traditional Medical Formulae Vol. 25, Issue 20, Pages: 121-124(2019)
- 作者机构：
  
  1.大理大学　药学与化学学院，云南　大理　 671000；
  2.大理大学　公共卫生学院，云南　大理　 671000
- 作者简介：
- 基金信息：
- DOI：10.13422/j.cnki.syfjx.20192015
  CLC： R284.2
- Received：23 May 2019，
  
  Published Online：09 July 2019，
  
  Published：20 October 2019
- 稿件说明：
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Shuang WANG, Yan-qiu SONG. Polyisoprenepolyols from Fruiting Bodies of Gymnopilus spectabilis[J]. Chinese journal of experimental traditional medical formulae, 2019, 25(20): 121-124.
DOI：

Shuang WANG, Yan-qiu SONG. Polyisoprenepolyols from Fruiting Bodies of Gymnopilus spectabilis[J]. Chinese journal of experimental traditional medical formulae, 2019, 25(20): 121-124. DOI： 10.13422/j.cnki.syfjx.20192015.

摘要

目的：

发现更多的高等真菌次级代谢产物，研究法国野生致幻真菌橘黄裸伞

Gymnopilus spectabilis

子实体的化学成分。

方法：

采用常压硅胶柱色谱、凝胶色谱和中压液相色谱、制备高效液相色谱等手段对橘黄裸伞子实体的三氯甲烷-丙酮-甲醇(1∶1∶1)提取物进行分离纯化，利用核磁共振波谱和高分辨质谱等方法鉴定化合物结构。

结果：

从法国野生真菌橘黄裸伞子实体中分离得到了6个多异戊二烯多醇类化合物，分别是gymnopilene A (1)，hypsiziprenol B

，A

(2～4)，gymnopilin A

，3a(5，6)。

结论：

化合物

为新化合物，命名为gymnopilene A。化合物

1～4

为首次从橘黄裸伞中分离得到。

Abstract

Objective:

To study the chemical constituents

especially hallucinogenic substances of fruiting bodies of

Gymnopilus spectabilis

from France.

Method:

The fruiting bodies of

spectabilis

were extracted with chloroform-acetone-methanol (1∶1∶1)

then the compounds were isolated and purified by silica gel column chromatography

gel chromatography

MPLC and preparative HPLC. Their structures were identified by spectroscopic analysis methods

such as 1D-NMR

2D-NMR and MS.

Result:

Six polyisoprenepolyols compounds were isolated and identified from fruiting bodies of

spectabilis

namely gymnopilene A (1)

hypsiziprenol B

(2-4)

ymnopilin A

3a(5-6).

Conclusion:

Compound 1is a new compound that is named gymnopilene A

and compounds 1-4are isolated from G.

spectabilis

for the first time.

关键词

Keywords

references

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Polyisoprenepolyols from Fruiting Bodies of Gymnopilus spectabilis

DOI：10.13422/j.cnki.syfjx.20192015

摘要

Abstract

关键词

Keywords

references