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纸质出版日期:2014
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初红梅, 曲桂武, 戴胜军, 等. 红参中美拉德反应产物研究[J]. 中国实验方剂学杂志, 2014,20(9):86-89.
CHU Hong-mei, QU Gui-wu, DAI Sheng-jun, et al. Study on Maillard Reaction Products from Chinese Red Ginseng[J]. Chinese journal of experimental traditional medical formulae, 2014, 20(9): 86-89.
初红梅, 曲桂武, 戴胜军, 等. 红参中美拉德反应产物研究[J]. 中国实验方剂学杂志, 2014,20(9):86-89. DOI: 10.13422/j.cnki.syfix.2014090086.
CHU Hong-mei, QU Gui-wu, DAI Sheng-jun, et al. Study on Maillard Reaction Products from Chinese Red Ginseng[J]. Chinese journal of experimental traditional medical formulae, 2014, 20(9): 86-89. DOI: 10.13422/j.cnki.syfix.2014090086.
目的:对红参Panax ginseng C.A.Meyer.中的美拉德反应产物进行研究。方法:采用硅胶柱色谱、Sephadex LH-20柱色谱、制备薄层及高效液相色谱等方法分离化合物,根据理化性质和波谱数据鉴定其结构。结果:分离并鉴定了9个化合物,分别为丙酮-1-O-α-D-甘露糖苷(1),5-羟甲基糠醛(2),3-羟基-2-甲基-4-吡喃酮(3),烟酸(4),4-甲氧基烟酸(5),异麦芽酚-3-O-α-D-甘露糖苷(6),阿魏酸(7),对羟基桂皮酸(8),芒柄花素(9)。结论:化合物1~6为美拉德反应产物,7~8为苯丙酸类化合物,9为异黄酮类化合物;其中化合物1为新化合物,化合物4~5及7~9均为首次从红参中发现。
Objective: To investigate the Maillard reaction products from Chinese red Ginseng. Method: The compounds were isolated and purified by column chromatography over silica gel and Sephadex LH-20
preparative TLC and preparative HPLC. The structures were elucidated by means of physico-chemical properties and spectral data. Result: Nine compounds were separated and identified as:ketopropyl-1-O-α-D-mannopyranoside (1)
5-hydroxymethyl-2-furfural (2)
3-hydroxyl-2-methyl-pyrone (3)
nicotinic acid (4)
4-methyoxyl nicotinic acid (5)
isomaltol-3-O-α-D-mannopyranoside (6)
ferulic acid (7)
p-hydroxycinnamic acid (8)
formononetin (9). Conclusion: Compounds 1-6 were attainable to Maillard reaction products
7-8 due to phenylpropionic acids and 9 due to isoflavone
furthermore
compound 1 was a new one
and compounds 4-5 and 7-9 were obtained from Chinese red Ginseng for the first time.
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