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南京中医药大学 江苏省中药资源产业化过程协同创新中心,中药资源产业化与方剂创新药物国家地方联合工程研究中心,国家中医药管理局中药资源循环利用重点研究室,江苏省中药功效物质重点实验室,南京 210023
刘圣金,博士,副教授,从事中药鉴定、质量标准及矿物药研究,Tel:025-85811511,E-mail: 13770653305@139.com
吴德康,教授,从事中药鉴定、质量标准及矿物药研究,Tel:025-85811511,E-mail: wudekang2008@126.com
收稿日期:2018-09-02,
网络出版日期:2018-11-06,
纸质出版日期:2019-03-05
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刘圣金, 吴超颖, 马瑜璐, 等. 不同矿物成因禹余粮质量评价及优质矿产资源筛选[J]. 中国实验方剂学杂志, 2019,25(5):14-20.
Sheng-jin LIU, Chao-ying WU, Yu-lu MA, et al. Quality Evaluation and Selection of High Quality Mineral Resources of Limonitum from Different Mineral Genesis[J]. Chinese journal of experimental traditional medical formulae, 2019, 25(5): 14-20.
刘圣金, 吴超颖, 马瑜璐, 等. 不同矿物成因禹余粮质量评价及优质矿产资源筛选[J]. 中国实验方剂学杂志, 2019,25(5):14-20. DOI: 10.13422/j.cnki.syfjx.20190412.
Sheng-jin LIU, Chao-ying WU, Yu-lu MA, et al. Quality Evaluation and Selection of High Quality Mineral Resources of Limonitum from Different Mineral Genesis[J]. Chinese journal of experimental traditional medical formulae, 2019, 25(5): 14-20. DOI: 10.13422/j.cnki.syfjx.20190412.
目的:
2
对不同矿物成因禹余粮进行矿物成分及含量分析,评价不同矿物成因禹余粮质量,并筛选禹余粮优质矿产资源。
方法:
2
通过偏光显微镜及X射线衍射技术分析不同样品矿物成分组成及其含量,以针铁矿含量作为评价指标。应用SPSS 16.0统计软件对不同样品矿物成分进行分层聚类分析。
结果:
2
淋滤浸染型禹余粮主要由褐铁矿、石英、伊利石、云母高岭石组成,沉积型禹余粮主要由褐铁矿、石英、钠长石组成,蚀变残留型禹余粮主要由褐铁矿、石英、透辉石、阳起石组成。江西产沉积型禹余粮针铁矿含量最高(46.4%),其次为江苏产淋滤浸染型(17.9%),山东产淋滤浸染型含量最低(0.5%)。沉积型针铁矿含量均高于12.0%,淋滤浸染型在0.5%~18.0%,含量差异较大,蚀变残留型在3.0%以下。对不同样品所含矿物成分进行聚类分析,淋滤浸染型6个样品聚为一类,沉积型3个样品聚为一类,蚀变残留型2个样品聚为一类。
结论:
2
江西产沉积型禹余粮质量最好。总体而言,沉积型质量整体较好,优于淋滤浸染型,淋滤浸染型优于蚀变残留型。
Objective:
2
To evaluate the quality of Limonitum from differentmineral genesis and select its high qualitymineral resources by analyzing itsmineral compositions and content.
Method:
2
Themineral compositions and content of different samples were analyzed by polarizing microscope and X-ray diffraction
and goethite content was taken as the evaluation index. SPSS 16.0 statistical software was used for hierarchical cluster analysis of themineral compositions in different samples.
Result:
2
Limonite
quartz
illite and mica kaolinite were the main components of Limonitum from leaching disseminated type. Sedimentary type limonite was mainly composed of limonite
quartz and albite. Residual-alteration type limonite was mainly composed of limonite
quartz
diopside and carnallite. The content of goethite in limonite was highest (46.4%) in sedimentary type limonite from Jiangxi province
followed by that in leaching-disseminated type from Jiangsu province (17.9%) and leaching-disseminated type from Shandong province (0.5%). The content of sedimentary goethite was higher than 12.0%and the content of leaching-disseminated type goethite was between 0.5%and 18.0%
with significant difference; and the content of residual-alteration type was below 3.0%. Cluster analysis ofmineral components in different samples showed that 6 samples of leaching-dissemination type were clustered into one group
3 samples of sedimentation type were clustered into one group
and 2 samples of residual-alteration type were clustered into one group.
Conclusion:
2
The quality of sedimentary type Limonitum in Jiangxi is the best. Generally
the quality of sedimentary type is better than that of leaching-disseminated type
and the quality of leaching disseminated type is better than that of residual-alteration type.
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